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Chapter One: Introduction ............................................................................ 1
- Study Goals And Objectives ................................................................. 1
- Reasons For Doing The Study .............................................................. 2
- Intended Audience .................................................................................... 2
- Scope Of Report .......................................................................................... 3
- Methodology ............................................................................................... 3
- Information Sources ............................................................................... 4
- Analyst Credentials ................................................................................ 4
- Related Bcc Reports ................................ 5
- Bcc Online Services .................................................................................. 5
- Disclaimer ..................................................................................................... 5
Chapter Two: Summary ....................................................................................... 6
- Summary .......................................................................................................... 6
- Summary Table Global Pemfc Mea Market, Through 2015($ Millions) ...................................................................................................... 7
- Summary Figure Global Pemfc Mea Market, Through 2015 ($ Millions) ...................................................................................................... 7
Chapter Three: Proton Exchange Membrane Fuel Cell Overview .................................................... 8
- Fuel Cell Technology ............................................................................... 8
- Proton Exchange Membrane Fuel Cell Fundamentals ........ 9
- Proton Exchange Membrane ¡¦ (Continued) .................... 10
- Figure 1 Generic Pemfc Diagram Showing Components ............ 11
- Fuel And Fuel Reforming Fundamentals......................... 12
- Improved Hydrogen Separation .................................................. 12
- Filtering Hydrogen And Oxygen ................................................. 13
- Georgia Tech Analysis Of Fuel Cell Failure Modes .................... 14
- Georgia Tech Analysis ¡¦ (Continued) ............................. 15
- The Direct Methanol Fuel Cell Variation ...................... 16
- The Direct Methanol Fuel Cell Variation (Continued) .............. 17
- Figure 2 Schematic Dmfc Chemistry ................................................... 18
- Proton Exchange Membrane Fuel Cell Companies ............... 18
- Table 1 Pemfc And Dmfc Makers ............................................................. 19
- Proton Exchange Membrane Fuel Cell Market Drivers .............................................. 20
- Market Segmentation And Industry Concentration ....................................................... 21
- Market Segmentation And ¡¦ (Continued) ................................. 22
- Portable Market Sector Market Drivers And Market Factors ....................... 22
- Table 2 Types Of Portable Products ............................. 23
- Table 3 Important Portable Product Concepts ........................... 24
- Table 3 (Continued) ........................................................................................ 25
- Table 4 Portable Fuel Cell Market Drivers ................................... 26
- Table 5 Portable Fuel Cell Market Factors .................................. 27
- Stationary Market Sector Market Drivers And Market Factors ..................... 27
- Uninterruptible Power Supplies ...................................... 27
- Combined Heat And Power ............................................... 28
- Utility Load Leveling ........................................................ 28
- Utility ¡¦ (Continued) ................................................. 29
- Stationary Market Drivers ............................................... 30
- Table 6 Stationary Fuel Cell Market Drivers .............................. 30
- Table 7 Stationary Fuel Cell Market Factors .............................. 31
- Transportation Market Sector Market Drivers And Market Factors ....................................................................... 31
- Table 8 Transportation Fuel Cell Market Drivers .................... 32
- Table 9 Transportation Fuel Cell Market Factors ................... 32
- ¡°Other¡± Market Sector Market Drivers And Market Factors .................................................................................... 32
- Portable Military Products ............................................... 33
- Table 10 Selected Portable Battery-powered Military Product Roles ............................. 33
- Recreational Vehicles........................................................ 33
- Anti-idling Power .............................................................. 34
- ¡°Other¡± Market Drivers .................................................... 35
- Table 11 ¡°Other¡± Fuel Cell Market Drivers ..................................... 35
- Table 12 ¡°Other¡± Fuel Cell Market Factors .................................... 35
- Global Pemfc Market Forecasts .......................................... 36
- Table 13 Global Pemfc Market By Application, Through 2015 ($ Millions) ........................................................................................... 36
- Figure 3 Global Pemfc Market By Application, 2010 ($Millions) ............................................. 36
- Table 14 Global Pemfc Market By Region, Through 2015 ($Millions) ..................................... 37
- Figure 4 Global Pemfc Market By Region, 2010 ($ Millions) ...... 37
- Optimistic And Pessimistic Scenarios ......................................... 37
- Optimistic And Pessimistic ¡¦ (Continued) ...................... 38
- Optimistic And Pessimistic ¡¦ (Continued) ...................... 39
- Table 15 Global Pemfc Market By Application, Through 2015 ($ Millions) ........................................... 40
- Table 15 (Continued) ...................................................................................... 41
Chapter Four: Membrane Electrode Assemblies ............................. 42
- Membrane Electrode Assembly Background ........................... 42
- Figure 5 Schemat Ic Simple Mea .............................................................. 43
- Performance Goals For Meas ............................................................ 44
- Table 16 Fuel Cell Mea Performance Goals .................................... 45
- Mea Fabrication And Assembly ......................................................... 45
- Figure 6 Schematic For Conceptual Mea Creation ..................... 46
- Mea Fabrication And Assembly (Continued) ................... 47
- Membrane Electrode Assembly Functional Stack Designs ................................ 48
- Electrochemistry ........................................................................ 48
- Water Management ...................................................................... 49
- Ancillary Factors ........................................................................ 50
- Membrane Electrode Assembly Development Approaches ................................... 51
- 3m Innovative Properties Co. Approach ..................................... 51
- Dupont Approach ........................................................................ 52
- Gm Approach ............................................................................... 53
- Hoku Scientific Approach ............................................................ 53
- Pemeas/E-tek Approach .......................................................... 53
- Palcan Power Systems Approach ................................................ 54
- Relion/Avista Approach .............................................................. 54
- Gore Approach ......................................... 55
- Other Approaches ........................................................................ 56
- Carbon Corrosion And Graphites ......................................... 56
- Carbon Corrosion And Graphites (Continued) ........................... 57
- Asbury Graphite Mills Approach ................................................ 58
- Crystal Graphite Approach ......................................................... 58
- Timcal Synthetic Graphite Approach ......................................... 58
- Direct Methanol Fuel Cell Mea Approaches ................. 58
- Gillette Co. ................................................................................... 58
- Sony Corp. .................................................................................... 59
- Los Alamos National Laboratory ................................................ 59
- California Institute Of Technology .............................................. 60
- University Of Connecticut ........................................................... 60
- Direct Methanol Fuel Cell Corp. ................................................. 60
- Direct Methanol ¡¦ (Continued) ....................................... 61
- Gore Dmfc .................................................................................. 62
- Maxdem Technologies ................................................................. 63
- Russian Academy Of Sciences ...................................................... 63
- Ube Industries, Ltd. .................................................................... 63
- Sumitomo Metal Approach .......................................................... 64
- Oorja Approach ............................................................................ 64
- Oorja Approach (Continued) ............................................. 65
- Oorja Approach (Continued) ............................................. 66
- Panasonic Approach .................................................................... 67
- Table 17 Panasonic Dmfc Specifications ........................................... 68
- University Of Dayton Approach ................................................... 68
- Arizona State University ............................................................. 69
- Rice University Approach ........................................................... 70
- Drexel University Approach ........................................................ 71
- Global Mea Component For Pemfcs Structure And Forecast .................................................................................................. 72
- Membrane Electrode Assembly Industry Structure .................................................................................... 72
- Table 18 Estimated Mea Company Market Shares, 2010 (%) ........ 73
- Bipolar Plate Market Structure ......................................... 74
- Gas Diffusion Layers And Carbon Structure ................ 74
- Ink And Catalyst Structure ................................................... 74
- Putting It All Together: Mea Market Forecast ........... 75
- Table 19 Global Mea Component Market, Through 2015 ($Millions) .................................. 75
- Figure 7 Global Mea Market Shares, 2010 (%) ................................... 76
- Table 20 Global Mea Component Market By Region, Through 2015 ($ Millions) ......................... 77
- Proton Exchan Ge Membranes For Fuel Cells .......................... 77
- Membrane Background .............................................................. 77
- Types Of Membranes .................................................................... 77
- Membrane Processes ................................................................... 78
- Proton Exchange Membrane Fuel Cell Membranes .................. 78
- What Makes A Good Pem Fuel Cell Membrane? ......................... 79
- Proton Exchange Membrane Functional Factors ...... 79
- Proton Exchange Membrane Functional ¡¦ (Continued) ........... 80
- Table 21 Membrane Parameter Variables ......................................... 81
- Proton Exchange Membrane Electrolyte Compatibility Factors .......................... 81
- Table 22 Pem Electrolyte Issues .................................... 82
- Membrane Temperature Tolerance Factors ................. 82
- High-temperature Tolerance ...................................................... 82
- Table 23 Advantages Of A Higher Temperature Membrane For A Pem Fuel Cell .......................................................... 83
- Freezing Temperature Tolerance ................................................ 83
- Membrane Water Tolerance Factors ................................. 84
- Figure 8 Water Transport In A Pem Fuel Cell ................................ 85
- Protonated Water Clusters ......................................................... 86
- Fuel Tolerance Factors ............................................................ 86
- Fuel Cell Membrane Structure ............................................ 87
- Membrane Fabrication And Synthesis .......................................... 88
- Table 24 Approaches To Fuel Cell Ionomer Synthesis .............. 89
- Table 25 Membrane Fabrication Technique .................................... 89
- Phase Separation .......................................................................... 90
- Casting Solvent ............................................................................. 91
- Ethylene Glycol As Solvent .......................................................... 91
- Impact Of Membrane Thickness ............................................. 91
- Membrane Functionalization ................................................ 92
- Membrane Pretreatment ............................................................. 93
- Membrane Material Compositions .................................................. 93
- Perfluorinated Polymer Membranes ................................ 94
- Perfluorocarbonsulfonic Acid Ionomers ...................................... 95
- Nafion Pfsa Membranes ............................................................ 96
- Table 26 Fundamental Properties Of Nafion Pfsa Membranes........................................... 97
- Gore Select ................................................................................... 98
- Table 27 Conductance Comparisons .................................................... 99
- Aciplex ........................................................................................ 100
- Flemion ...................................................................................... 101
- Polytetrafluoroethylene Durability Enhancement ................... 101
- Berkeley Lab¡¯S Materials Sciences Division And Uc Berkeley¡¯S Department Of Chemical Engineering Polymer Me Mbrane ............. 102
- Berkeley Lab¡¯S Materials Sciences ¡¦(Continued) ................... 103
- University Of Rochester Thin Filter ............................... 104
- Polyfuel Hydrocarbon Membrane .................................... 105
- Polyfuel Hydrocarbon Membrane (Continued) ......................... 106
- Polyfuel Hydrocarbon Membrane (Continued) ......................... 107
- Mit And The University Of Pennsylvania Nanocomposite Membrane Barriers ............................ 108
- Toray Industries Hydrocarbon Membrane ................... 109
- Akron Polymer Systems Approach ..................................... 110
- Daychem Laboratories Approach ....................................... 110
- Jsr Multilayered Structure ................................................ 111
- Ballard Power Systems Bam Membranes ........................ 111
- Modified Polystyrene Sulfonated Membranes.......... 112
- Victrex Polyether Ether Ketone (Peek) ......................... 113
- Hoku Scientifics Sek Membrane .......................................... 114
- University Of Calgary .............................................................. 115
- Tosoh¡¯S Poly(Arylene Ether Sulfone) .............................. 115
- Sulfonated Poly(Arylene Ether) Sulfones .................. 115
- Sulfonated Poly(Arylene Ether) Sulfones (Continued) ............ 116
- Table 28 Virginia Tech Bps Membrane Properties Compared With Nafion 117 ................................................................... 117
- Functionalization And Direct Synthesis Of Sulfonated Membranes ........................................................................... 117
- Reduced Electro-osmotic Drag ................................................. 118
- Conductivity ............................................................................... 119
- Argonne National Lab Dendritic Sulfonated Polyaryl Ether .......................................... 119
- Dais Analytic Sulfonation Of Styrene Containing Block Copolymers ....................................... 120
- Ethylene Styrene Interpolymers ............................................... 121
- Polystyrene Sulfonic Acid/Polyvinyl Alcohol Blend ................. 121
- Gas Technology Institute Membrane........................................ 121
- Sulfonated Perfluorocyclobutane .............................................. 121
- Heterocyclic And Polybenimidizole Membranes ...... 122
- Pemeas And Celtec .................................................................. 122
- University Of Texas Variations Of Pbi Membrane ................... 123
- Plug Power And Doe And Pbi .................................................. 123
- Renssalaer¡¯S Chain-transfer (Raft) Polymerization ............. 124
- Samsung Polyimide Derivative ................................................. 124
- Other Modifications Of Pbi........................................................ 125
- Sulfonated Polyimides ............................................................ 126
- Tailored Imides .......................................................................... 126
- Poly(Bisbenzoxazole) [Pbo] ..................................................... 127
- University Of Massachusetts Co-polymers .................. 127
- Composite Membranes .............................................................. 128
- Aciplex And Titanias .................................................................. 128
- Inorganic-organic Composite ................................................... 129
- Modified Siloxane (Ormosil) ................................................. 130
- Organic/Heteropolyacids And Nafion ........................................ 130
- Aniline And Perfluorosulfonic Acid Polymer ............................ 131
- Random Fibers And Perfluorinated Membranes ...................... 131
- Ionic Gel Fill .............................................................................. 132
- Zirconium Phosphonate Fill ...................................................... 132
- Oxidation Resistant Carbon Supports ...................................... 133
- Novel And Experimental Pem Materials ........................ 133
- Basf Polyurethane Elastomer ................................................. 134
- Georgia Tech Triazole Booster .................................................. 134
- Dow Xus 13204.1 ...................................................................... 134
- Altergy Freedom Power ............................................................. 135
- 3m Acid Functional Fluoropolymers Membrane ...................... 135
- Glass Membranes ...................................................................... 136
- Microcell Microfiber ................................................................... 137
- Oak Ridge National Lab Metallized Bio-cellulosics ................ 137
- University Of Florida Intermediate-temperature Proton-conducting Membranes ....................................................... 138
- Membrane Companies ........................................................................... 139
- Table 29 Companies Producing Ion Selective Membranes For Pem Fuel Cells ................................................................................. 140
- Table 30 Estimated Pemfc Fluoropolymer Membrane Company Market Shares, 2010 (%)...................................................... 141
- Asahi Glass Co., Ltd. .................................................................... 141
- Asahi Kasei Chemicals Corp. .................................................. 142
- Ballard Power Systems ........................................................... 143
- U.S. Headquarters ..................................................................... 143
- U.S. Headquarters (Continued) ..................................... 144
- Dais Analytic Corp. ..................................................................... 145
- Dupont Fuel Cells ...................................................................... 145
- Dupont Fuel Cells (Continued) .................................. 146
- Giner Electrochemical Systems, Llc ............................... 147
- Golden Energy Fuel Cell Co., Ltd. ..................................... 148
- Gore Fuel Cell Technologies .............................................. 148
- Hoku Scientific, Inc. .................................................................. 149
- Hydrogenics Corp. ...................................................................... 150
- Idatech, Llc .................................................................................... 151
- Jsr Corp. ............................................................................................ 152
- Maxdem, Inc. (Combridge Display) ....................................... 152
- Plug Power ..................................................................................... 153
- Plug Power (Continued) ............................................................ 154
- Polyfuel .......................................................................................... 155
- Relion ................................................................................................ 155
- Toray Industries, Inc. ............................................................... 156
- United Technology Corp. Fuel Cells ............................... 156
- Others ............................................................................................... 157
- Global Pemfc Membrane Market Structure And Forecast ................................................................................................ 158
- Pem Membrane Materials Market Share ........................ 158
- Table 31 Proton Exchange Membrane Material By Type,2010 Versus 2015 (%) ............................................ 158
- Pem Membrane Materials Value .......................................... 158
- Table 32 Global Proton Exchange Membranes For Pemfcs Market By Application, Through 2015 ($Millions) .............................. 159
- Table 33 Global Proton Exchange Membranes For Pemfcs Market By Region, Through 2015 ($ Millions)............ 159
Chapter Five: Mea, Gaseous Diffusion Layers, And Bipolar Plates ..................................................... 160
- Gaseous Diffusion Layers ................................................................. 160
- Gaseous Diffusion Layer Background ............................ 160
- Attributes Of Gas Diffusion Layers .................................. 161
- Table 34 Attributes Needed For Gas Diffusion Layer Materials ......................................... 162
- Gas Diffusion Layer Manufacturing ................................ 163
- Table 35 Pros And Cons Of Gdl Manufacturing Techniques ........................................... 163
- Developments At Graftech International ................................. 164
- Developments At ¡¦ (Continued) .................................... 165
- Developments At Umicore Ag ................................................... 166
- Developments At Ballard Material Products ............................ 167
- Developments At Johnson Matthey .......................................... 168
- Developments At Lydall, Inc. .................................................... 168
- Developments At Mitsubishi Rayon .......................................... 169
- Developments At Sgl Carbon Group ....................................... 169
- Table 36 Typical Properties Of Sigracet Gas Diffusion Layer .................................................. 170
- Developments At Toray/Mitsui .................................................. 170
- Developments At Rensselaer Polytechnic Institute ................. 171
- Developments At Zoltek ............................................................. 172
- Developments At Cabot And Ird Fuel Cell ............................... 172
- Other Developments .................................................................. 173
- Bipolar Plates ......................................................................................... 174
- Bipolar Plate Background .................................................... 174
- Bipolar Plate Designs ............................................................... 175
- Table 37 Design Considerations For Bipolar Plates ................ 175
- Table 38 Material Types For Bipolar Plates ................................. 176
- Corrosion Protection Of Metallic Plates .................................... 176
- Ballard Powers¡¯ Bipolar Metal Plate .............................. 176
- Surface Modification ....................................................... 177
- Tech-etch Metal Plates ............................................................. 177
- Ecpower/Sorapec Approach ...................................................... 177
- Entegris Approach ..................................................................... 178
- Generics Porous Plates Approach ............................................. 178
- T8 Series .................................................................................... 179
- Idatech Layered Bipolar Plate Assembly ................................ 179
- Use Of Thermoplastic ................................................................. 180
- Intelligent Energy¡¯S Proprietary Design................................... 180
- Nisshinbo Approach ................................................................... 181
- Pem Plates Approach ............................................................... 182
- Illinois Urbana-champaign Fuel Cell Separator Plate Having Controlled Fiber Orientation .................................. 182
- Plug Power Assembly ................................................................ 183
- Porvair Approach ....................................................................... 184
- Sgl Technologies Approach ..................................................... 184
- Table 39 Sgl Bipolar Plate Typical Properties ........................... 185
- Bac2 Electrophen ...................................................................... 185
- Improved Gasket Approach ....................................................... 186
- Acal Platinum-free Cathode ................................................... 187
- Acal Platinum-free ¡¦ (Continued) .............................. 188
- Federal-mogul¡¯S Liquid Elastomer Molding ............................. 189
- Aeg Carbon Fiber-elastomer Composite Bipolar Plates ........ 189
- Myfc Polymer Electrolyte Membrane Fuel Cell Fuelcellsticker ..................................................................... 190
- Dmfc Anode Approaches .......................................................... 191
- Toshiba Approach ...................................................................... 191
- Dupont Gen Iv Approach ........................................................ 192
- Medis Conductive Polymer Approach ....................................... 193
- Generics Cmr Approach ........................................................... 194
- Energy Ventures Research Approach ....................................... 194
- Polyfuel Approach .................................................................... 195
- Smart Fuel Cell Approach ......................................................... 195
- Mea, Gdl, And Bipolar Plate Companies ...................................... 196
- 10x Microstructures ................................................................. 196
- 3m ......................................................................................................... 196
- Asbury Graphite ........................................................................... 197
- Ballard Power Systems ........................................................... 197
- Dixon Ticonderoga Co. .............................................................. 197
- Daimler ............................................................................................. 197
- Mitsubishi Fuso ......................................................................... 198
- Orion Bus Industries (Daimler Buses North America) ............ 198
- Smart Gmbh .............................................................................. 198
- Smart Gmbh (Continued) ......................................................... 199
- Smart Gmbh (Continued) ......................................................... 200
- Dupont Fuel Cell ........................................................................ 201
- Elec Trochem, Inc. ....................................................................... 202
- Entegris, Inc. ................................................................................. 203
- General Electric ........................................................................ 203
- General Motors, Corp. .............................................................. 204
- Gore Fuel Cell Technologies .............................................. 205
- Graftech International, Ltd. .............................................. 206
- Hoku Scientific, Inc. .................................................................. 207
- Hoku Scientific, Inc. (Continued) .............................................. 208
- Hydrogenics Corp. ...................................................................... 209
- Honda ................................................................................................. 209
- Honda U.S. Headquarters ......................................................... 209
- Horizon Fuel Cells And Riversimple ................................ 210
- Horizon Fuel Cells And Riversimple (Continued) .................... 211
- Icm Plastics .................................................................................... 212
- Johnson Matthey Fuel Cells Research .......................... 212
- Johnson Matthey Fuel Cells (Usa) .......................................... 213
- Lynntech ......................................................................................... 213
- Manhattan Scientifics, Inc. ................................................... 214
- Research Headquarters ............................................................. 214
- Materials And Electrochemical Research Corp. ...... 214
- Mitsubishi Rayon Co., Ltd. ....................................................... 215
- Morgan Crucible Co. .................................................................. 215
- Morphic Technologies ............................................................. 215
- Nedstack Fuel Cell Technology ........................................ 216
- Nisshinbo Industries, Inc. ....................................................... 217
- Nuvera Fuel Cells ...................................................................... 217
- Nuvera Fuel Cells Europe ......................................................... 217
- Palcan Fuel Cells, Ltd. ............................................................ 217
- Plug Power ..................................................................................... 218
- Porvair Fuel Cell Technology ............................................ 218
- Protonex Technology Corp. .................................................. 218
- Relion/Avista Labs ...................................................................... 219
- Sgl Carbon ...................................................................................... 219
- Sgl Technik .............................................................................. 220
- Sharp Corp. ...................................................................................... 220
- Smart Fuel Cell Ag (Sfc) .......................................................... 221
- Smart Fuel Cell Ag (Sfc) (Continued) .................................... 222
- Spectracorp ................................................................................... 223
- Sumitomo Metals ......................................................................... 223
- Superior Graphite Co. ............................................................... 224
- Tiax ...................................................................................................... 224
- Ticona ................................................................................................ 225
- Timcal Graphite & Carbon ...................................................... 225
- Toray Industries, Inc. ............................................................... 226
- Unidym (Arrowhead Research Corp.) ................................ 226
- Utc Power ........................................................................................ 227
- Zoltek Materials Group .......................................................... 227
- Global Bipolar Plates And Gdls For Pemfcs Structure Forecast ........................................................................ 227
- Table 40 Global Pemfc Bipolar Plate And Carbon Market By Application, Through 2015 ($ Millions) ................................... 228
- Figure 9 Global Pemfc Bipolar Plate And Carbon Market By Application, 2006-2015 ($ Millions) .............................................. 228
- Figure 10 Global Market Shares Of Pemfc Bipolar Plate And Carbon By Type, 2010 (%) ................................................................ 229
- Table 41 Global Pemfc Bipolar Plate And Carbon Market By Region, Through 2015 ($ Millions) ............................................. 229
Chapter Six: Catalysts And Inks .............................................................. 230
- Background .............................................................................................. 230
- Catalyst Durability .................................................................. 230
- Catalyst Particle Size .............................................................. 231
- Catalyst Coated Membranes ................................................. 231
- Dupont Approach ...................................................................... 232
- Polyfuel Approach .................................................................... 233
- Aerogel Composite Approach .................................................... 233
- Figure 11 Preparation Of Carbon Aerogel Supported Platinum .................................. 234
- Gs Carbon Approach ................................................................. 234
- Gs Carbon Approach (Continued) .................................. 235
- Ramot University Approach ...................................................... 236
- Low Catalyst Loading Approaches .................................... 236
- Ballard Approach ....................................................................... 236
- Combinatorial Catalyst Techniques ............................... 237
- Innovative Materials And Nanomaterials .................... 237
- Platinum Alloys ......................................................................... 238
- Anode Durability ....................................................................... 239
- Nanoparticles ............................................................................. 240
- Kyoto University ............................................................. 240
- Hong Kong University Of Science And Technology ........ 240
- Los Alamos National Laboratory And Brookhaven National Laboratory .................................................. 240
- Brown University ............................................................ 241
- Brook Haven National Laboratory .................................. 242
- University Of Central Florida ......................................... 243
- Cornell University .......................................................... 244
- Georgia Tech And Xiamen University ............................ 245
- Georgia Tech ¡¦ (Continued) ................................... 246
- Mit Researchers Take First Atomic-scale Compositional Images Of Fuel Cell Nanoparticles ............................................................. 247
- Nanofibers .................................................................................. 248
- Nanofibers (Continued) .................................................. 249
- Nanolevel Platinum/Carbon Electrocatalyst For Cathode ........ 250
- University Of Wisconsin-madison Nanoparticle Catalyst ........ 250
- University Of Houston Lattice-strained Core-shell Nanoparticle Catalyst .......................................................... 251
- Acta Base Metal Cathode Catalyst ........................................... 252
- Lawrence Berkeley And Argonne National Laboratories Alloy ................ 253
- Lawrence Berkeley ¡¦(Continued) ................................. 254
- Lawrence Berkeley ¡¦(Continued) ................................. 255
- Lawrence Berkeley ¡¦(Continued) ................................. 256
- Nanowires .................................................................................. 257
- University Of Rochester Sizing Nanowires .................... 257
- Jet Propulsion Laboratory Nanophase Nickel-zirconium Alloy Approach ................................................ 258
- University Of Texas At Austin Palladium-based Alloy Catalysts .............................................................. 259
- Tiax, Llc Nanostructured Thin Film Catalysts .................... 260
- Tiax, Llc ¡¦ (Continued) .............................................. 261
- Figure 12 Projected Cost At High Volume Manufacturing (%) ........................................................ 262
- Table 42 Performance And Cost Summary ...................................... 263
- Sdk High-efficiency Catalysts Platinum Substitute For Pefcs ............................................................... 264
- Washington University In St. Louis Bimetallic Fuel Cell Catalyst ...................................... 265
- Simple Tech Heterogeneous Catalysis Technology .................. 266
- Brown University Platinum Nanocubes ................................... 267
- Johnson Matthey Fuel Cells, Ltd. And The Neclass Project ........................................... 268
- University Of Rochester ¡°Black Metal¡± Approach .................... 268
- Transition Metal Nanosized Catalysts ..................................... 269
- Texas Tech University Platinum Nanodots ............................. 270
- Catalyst Ink Compositions ............................................................... 270
- Applied Research & Development Israel Formulation ..................................... 271
- Other Catalyst Ink Formulations ..................................... 271
- Sw Research And Gore Approach ............................................. 271
- Utc Fuel Cells Approach .......................................................... 272
- Jet Propulsion Laboratory Approach ........................................ 272
- Angstron Materials Graphene .................................................. 272
- Northwestern University And The Mccormick School Of Engineering And Applied Science Graphene Films ............ 273
- Samsung Electronics Approach ................................................ 274
- Carbon Composite Electrocatalyst Powders ....................... 274
- Cabot Approach ............................................................................ 275
- Asymtek Jet Dispensing Approach ...................................... 276
- Catalyst And Ink Companies ............................................................ 277
- Acta Spa ............................................................................................ 277
- Alfa Aesar-johnson Matthey Co. ........................................ 277
- Johnson Matthey Co. ................................................................. 278
- Anglo Platinum ............................................................................ 279
- Aquarius Platinum Pty, Ltd. .................................................. 280
- Basf Corp. ......................................................................................... 280
- Basf Corp. (Continued) ............................................................ 281
- Basf Corp. (Continued) ............................................................ 282
- Impala Platinum Holding, Ltd. (Implats) ......................... 283
- Impala Platinum Holding (U.K.) .............................................. 283
- Lonmin Platinum, Plc ................................................................ 283
- Lonmin South Africa ................................................................. 284
- Norilsk Nickel .............................................................................. 284
- Stillwater Mining....................................................................... 284
- Om Group, Inc. ................................................................................ 285
- Quantumsphere, Inc. .................................................................. 286
- Stillwater ...................................................................................... 287
- Tanaka Precious Metals .......................................................... 287
- Global Pemfcs Catalyst And Ink Structure And Forecast ................................................................................................ 287
- Platinum Markets And Consumption ................................ 288
- Table 43 World Mine Production And Reserves: Mine Production Pgms (Kg) ............................................................................ 289
- Table 44 World Platinum Demand (Thousand Ozs) ...................... 289
- Palladium Markets And Consumption ............................. 290
- Palladium Markets And Consumption (Continued) ................. 291
- Catalyst And Ink Value ............................................................ 292
- Table 45 Global Pemfc Catalyst And Ink Market,Through 2015 ($ Millions) .................................................................... 292
- Figure 13 Global Pemfc Catalyst And Ink Market,Through 2015 ($ Millions) ..................................................................... 293
- Table 46 Global Pemfc Catalyst And Ink Market By Region, Through 2015 ($ Millions) .................................................. 293
Chapter Seven: Industry Structure And Competitive Aspects ....................................................... 294
- Industry Environment And Trade Practices .......................... 294
- Environmental Issues .............................................................. 295
- Environmental Issues (Continued) ........................................... 296
- Pemfc Regulatory Issues And Government Involvement ........................................ 297
- U.S. Doe Direct Pem Fuel Cell Funding ................................ 297
- Topic 1 Alternative Electrode Deposition Processes ..... 297
- Topic 2 Novel Mea Manufacturing ............................... 297
- Topic 3 Rapid Mea Conditioning .............................. 298
- Topic 4 Process Modeling For Fuel Cell Stacks .............. 298
- Topic 5 Process And Device For Cost Effective Testing Of Cell Stacks ................................................ 299
- Topic 6 Manufacturing Technologies For Reducing The Cost Of High-pressure Composite Conformable Tanks ................................................... 299
- U.S. Federal Fuel Cell Vehicle Funding ................................... 300
- U.S. Federal ¡¦ (Continued) ........................................... 301
- U.S. Federal ¡¦ (Continued) ........................................... 302
- U.S. Federal ¡¦ (Continued) ........................................... 303
- Overall U.S. Federal Fuel Cell Funding ................................... 304
- Table 47 2010 Budget Hydrogen And Fuel Cell Technologies Funding Profile By Subprogram ($Thousands) .................... 304
- Table 47 (Continued) .................................................................................... 305
- Overall U.S. Federal ¡¦ (Continued) .............................. 306
- U.S. Fuel Cell Council Analysis Of Funding Priorities ............ 307
- U.S. Fuel Cell ¡¦ (Continued) ......................................... 308
- Office Of Science ......................................................................... 309
- National Hydrogen Association ................................................ 310
- National Science Foundation .................................................... 310
- Department Of Defense .............................................................. 311
- Army Research Laboratory ............................................ 311
- Usaf Research Laboratory ............................................ 311
- Naval Research Laboratory ............................................ 312
- National Aeronautics And Space Administration (Nasa) ....... 312
- Jet Propulsion Laboratory .............................................. 312
- Global Incentives And Research Efforts ................................... 313
- Academic Institutions¡¯ Involvement In Fuel Cell Development ............................................................................ 314
- Table 48 Major Institutional Research Into Pem Fuel Cells .............................................................................................................. 314
- Mea Distribution Channels .............................................................. 315
- Industry Purchasing Influences And Prices ......................... 315
- Industry Purchasing Influences ¡¦ (Continued) ....... 316
- Industry Purchasing Influences ¡¦ (Continued) ....... 317
- Table 49 Historic Platinum Prices (Dollars Per Tr Oz) ........... 318
- Table 50 Historic Palladium Prices (Dollars Per Tr Oz) ......... 318
- Life-cycle Costs ........................................................................... 319
Title: Materials for Proton Exchange Membranes and Membrane Electrode Assemblies for PEM Fuel Cells
INTRODUCTION STUDY GOALS AND OBJECTIVES This analysis focuses on the three main components of the membrane electrode assembly (MEA) for proton exchange membrane fuel cell (PEMFC). These include: Membranes Gaseous diffusion layers and bipolar plates Catalysts and inks Polymer membranes that are the electrolyte and therefore the heart of the fuel cell, and they receive extra attention. The report also examines the history and advancing technology of these components, the companies involved in these developments, the current and projected incentives, and the projected markets for such technologies. Identified as a practical solution to many of the technological and environmental problems facing the world today, the proton exchange membrane (PEM) fuel cell is appropriate as a power source for transportation, stationary distributive power, and small-scale applications such as portable electronic products. Applications for all types of fuel cells are still evolving. In the process of this evolution, the different proton exchange membrane materials and MEAs will evolve and be adapted to more specific uses. Identifying how researchers are solving the search for better membranes that have greater tolerances to poisoning, greater durability, and lower costs is a major objective of the report. The U.S. Japanese, Chinese, and European Union governments are pouring billions of dollars of loans, subsidies, and outright grants into fuel cell research and development — and at the same time there has been a series of brutal confrontations between Congress and the President¡¯s administration over continued fuel cell vehicle funding. Meanwhile, European and Far Eastern government subsidies increase. Commercialization of the fuel cell is not solely influenced by engineers and scientists working on stacks and reformers. (This is also brought about by subsidies by the government, lobbying efforts, venture capitalists, and most of all by some consumers actually finding a need or desire for the product.) A major cost issue addressed is the critical issue of the catalyst component. REASONS FOR DOING THE STUDY Fuel cells are viewed as potential candidates for auxiliary power, mobile power, stationary distributed or central power, and portable product power. Advances in the technology are made, but sometimes these advances reveal even more challenges to be met. Slowly there is the realization that total dependency on hydrocarbon fuels is not a viable economic option. Proton exchange membrane fuel cells have a part in securing energy security for the country, improving the environment, greatly reducing urban pollution, and creating jobs in manufacturing as the technology advances. They can also provide a cost-effective and performance-driven rival for advanced batteries. This study analyzes components of the PEM fuel cell, a technology offering the promise of greatly reduced environmental impact and excellent performance, price, and efficiency advantages. Recent historic developments and approaches are described along with recent commercial developments and the state of the art. Hydrogen feed fuel cells are based on the electrochemical reaction between hydrogen and oxygen. This electrochemical process does not pollute the environment with hydrocarbons, particulates or any sulfur or nitrogen oxides. The study identifies the opportunities and technological requirements of the proton exchange membrane fuel cell and the MEA and the bipolar plates for the PEM fuel cell. When several units of the membrane electrode assembly are capped off with a bipolar plate and properly assembled, the arrangement is referred to as a stack. Questions to be answered include determining a timetable for PEM fuel cell commercialization, as well as what types of membranes and membrane assemblies are needed to make this possible.
SUMMARY FIGURE
GLOBAL PEMFC MEA MARKET, THROUGH 2015
($ MILLIONS)
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\ 1,397.60 |
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\ 9.0396 |
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\ 1,487.19 |
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\ 1,737.29 |
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