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Materials for Proton Exchange Membranes and Membrane Electrode Assemblies for PEM Fuel Cells
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Chapter One: Introduction ............................................................................ 1

  • Study Goals And Objectives ................................................................. 1
  • Reasons For Doing The Study .............................................................. 2
  • Intended Audience .................................................................................... 2
  • Scope Of Report .......................................................................................... 3
  • Methodology ............................................................................................... 3
  • Information Sources ............................................................................... 4
  • Analyst Credentials ................................................................................ 4
  • Related Bcc Reports ................................ 5
  • Bcc Online Services .................................................................................. 5
  • Disclaimer ..................................................................................................... 5

Chapter Two: Summary ....................................................................................... 6

  • Summary .......................................................................................................... 6
  • Summary Table Global Pemfc Mea Market, Through 2015($ Millions) ...................................................................................................... 7
  • Summary Figure Global Pemfc Mea Market, Through 2015 ($ Millions) ...................................................................................................... 7

Chapter Three: Proton Exchange Membrane Fuel Cell Overview .................................................... 8

  • Fuel Cell Technology ............................................................................... 8
  • Proton Exchange Membrane Fuel Cell Fundamentals ........ 9
  • Proton Exchange Membrane ¡¦ (Continued) .................... 10
  • Figure 1 Generic Pemfc Diagram Showing Components ............ 11
  • Fuel And Fuel Reforming Fundamentals......................... 12
  • Improved Hydrogen Separation .................................................. 12
  • Filtering Hydrogen And Oxygen ................................................. 13
  • Georgia Tech Analysis Of Fuel Cell Failure Modes .................... 14
  • Georgia Tech Analysis ¡¦ (Continued) ............................. 15
  • The Direct Methanol Fuel Cell Variation ...................... 16
  • The Direct Methanol Fuel Cell Variation (Continued) .............. 17
  • Figure 2 Schematic Dmfc Chemistry ................................................... 18
  • Proton Exchange Membrane Fuel Cell Companies ............... 18
  • Table 1 Pemfc And Dmfc Makers ............................................................. 19
  • Proton Exchange Membrane Fuel Cell Market Drivers .............................................. 20
  • Market Segmentation And Industry Concentration ....................................................... 21
  • Market Segmentation And ¡¦ (Continued) ................................. 22
  • Portable Market Sector Market Drivers And Market Factors ....................... 22
  • Table 2 Types Of Portable Products ............................. 23
  • Table 3 Important Portable Product Concepts ........................... 24
  • Table 3 (Continued) ........................................................................................ 25
  • Table 4 Portable Fuel Cell Market Drivers ................................... 26
  • Table 5 Portable Fuel Cell Market Factors .................................. 27
  • Stationary Market Sector Market Drivers And Market Factors ..................... 27
  • Uninterruptible Power Supplies ...................................... 27
  • Combined Heat And Power ............................................... 28
  • Utility Load Leveling ........................................................ 28
  • Utility ¡¦ (Continued) ................................................. 29
  • Stationary Market Drivers ............................................... 30
  • Table 6 Stationary Fuel Cell Market Drivers .............................. 30
  • Table 7 Stationary Fuel Cell Market Factors .............................. 31
  • Transportation Market Sector Market Drivers And Market Factors ....................................................................... 31
  • Table 8 Transportation Fuel Cell Market Drivers .................... 32
  • Table 9 Transportation Fuel Cell Market Factors ................... 32
  • ¡°Other¡± Market Sector Market Drivers And Market Factors .................................................................................... 32
  • Portable Military Products ............................................... 33
  • Table 10 Selected Portable Battery-powered Military Product Roles ............................. 33
  • Recreational Vehicles........................................................ 33
  • Anti-idling Power .............................................................. 34
  • ¡°Other¡± Market Drivers .................................................... 35
  • Table 11 ¡°Other¡± Fuel Cell Market Drivers ..................................... 35
  • Table 12 ¡°Other¡± Fuel Cell Market Factors .................................... 35
  • Global Pemfc Market Forecasts .......................................... 36
  • Table 13 Global Pemfc Market By Application, Through 2015 ($ Millions) ........................................................................................... 36
  • Figure 3 Global Pemfc Market By Application, 2010 ($Millions) ............................................. 36
  • Table 14 Global Pemfc Market By Region, Through 2015 ($Millions) ..................................... 37
  • Figure 4 Global Pemfc Market By Region, 2010 ($ Millions) ...... 37
  • Optimistic And Pessimistic Scenarios ......................................... 37
  • Optimistic And Pessimistic ¡¦ (Continued) ...................... 38
  • Optimistic And Pessimistic ¡¦ (Continued) ...................... 39
  • Table 15 Global Pemfc Market By Application, Through 2015 ($ Millions) ........................................... 40
  • Table 15 (Continued) ...................................................................................... 41

Chapter Four: Membrane Electrode Assemblies ............................. 42

  • Membrane Electrode Assembly Background ........................... 42
  • Figure 5 Schemat Ic Simple Mea .............................................................. 43
  • Performance Goals For Meas ............................................................ 44
  • Table 16 Fuel Cell Mea Performance Goals .................................... 45
  • Mea Fabrication And Assembly ......................................................... 45
  • Figure 6 Schematic For Conceptual Mea Creation ..................... 46
  • Mea Fabrication And Assembly (Continued) ................... 47
  • Membrane Electrode Assembly Functional Stack Designs ................................ 48
  • Electrochemistry ........................................................................ 48
  • Water Management ...................................................................... 49
  • Ancillary Factors ........................................................................ 50
  • Membrane Electrode Assembly Development Approaches ................................... 51
  • 3m Innovative Properties Co. Approach ..................................... 51
  • Dupont Approach ........................................................................ 52
  • Gm Approach ............................................................................... 53
  • Hoku Scientific Approach ............................................................ 53
  • Pemeas/E-tek Approach .......................................................... 53
  • Palcan Power Systems Approach ................................................ 54
  • Relion/Avista Approach .............................................................. 54
  • Gore Approach ......................................... 55
  • Other Approaches ........................................................................ 56
  • Carbon Corrosion And Graphites ......................................... 56
  • Carbon Corrosion And Graphites (Continued) ........................... 57
  • Asbury Graphite Mills Approach ................................................ 58
  • Crystal Graphite Approach ......................................................... 58
  • Timcal Synthetic Graphite Approach ......................................... 58
  • Direct Methanol Fuel Cell Mea Approaches ................. 58
  • Gillette Co. ................................................................................... 58
  • Sony Corp. .................................................................................... 59
  • Los Alamos National Laboratory ................................................ 59
  • California Institute Of Technology .............................................. 60
  • University Of Connecticut ........................................................... 60
  • Direct Methanol Fuel Cell Corp. ................................................. 60
  • Direct Methanol ¡¦ (Continued) ....................................... 61
  • Gore Dmfc .................................................................................. 62
  • Maxdem Technologies ................................................................. 63
  • Russian Academy Of Sciences ...................................................... 63
  • Ube Industries, Ltd. .................................................................... 63
  • Sumitomo Metal Approach .......................................................... 64
  • Oorja Approach ............................................................................ 64
  • Oorja Approach (Continued) ............................................. 65
  • Oorja Approach (Continued) ............................................. 66
  • Panasonic Approach .................................................................... 67
  • Table 17 Panasonic Dmfc Specifications ........................................... 68
  • University Of Dayton Approach ................................................... 68
  • Arizona State University ............................................................. 69
  • Rice University Approach ........................................................... 70
  • Drexel University Approach ........................................................ 71
  • Global Mea Component For Pemfcs Structure And Forecast .................................................................................................. 72
  • Membrane Electrode Assembly Industry Structure .................................................................................... 72
  • Table 18 Estimated Mea Company Market Shares, 2010 (%) ........ 73
  • Bipolar Plate Market Structure ......................................... 74
  • Gas Diffusion Layers And Carbon Structure ................ 74
  • Ink And Catalyst Structure ................................................... 74
  • Putting It All Together: Mea Market Forecast ........... 75
  • Table 19 Global Mea Component Market, Through 2015 ($Millions) .................................. 75
  • Figure 7 Global Mea Market Shares, 2010 (%) ................................... 76
  • Table 20 Global Mea Component Market By Region, Through 2015 ($ Millions) ......................... 77
  • Proton Exchan Ge Membranes For Fuel Cells .......................... 77
  • Membrane Background .............................................................. 77
  • Types Of Membranes .................................................................... 77
  • Membrane Processes ................................................................... 78
  • Proton Exchange Membrane Fuel Cell Membranes .................. 78
  • What Makes A Good Pem Fuel Cell Membrane? ......................... 79
  • Proton Exchange Membrane Functional Factors ...... 79
  • Proton Exchange Membrane Functional ¡¦ (Continued) ........... 80
  • Table 21 Membrane Parameter Variables ......................................... 81
  • Proton Exchange Membrane Electrolyte Compatibility Factors .......................... 81
  • Table 22 Pem Electrolyte Issues .................................... 82
  • Membrane Temperature Tolerance Factors ................. 82
  • High-temperature Tolerance ...................................................... 82
  • Table 23 Advantages Of A Higher Temperature Membrane For A Pem Fuel Cell .......................................................... 83
  • Freezing Temperature Tolerance ................................................ 83
  • Membrane Water Tolerance Factors ................................. 84
  • Figure 8 Water Transport In A Pem Fuel Cell ................................ 85
  • Protonated Water Clusters ......................................................... 86
  • Fuel Tolerance Factors ............................................................ 86
  • Fuel Cell Membrane Structure ............................................ 87
  • Membrane Fabrication And Synthesis .......................................... 88
  • Table 24 Approaches To Fuel Cell Ionomer Synthesis .............. 89
  • Table 25 Membrane Fabrication Technique .................................... 89
  • Phase Separation .......................................................................... 90
  • Casting Solvent ............................................................................. 91
  • Ethylene Glycol As Solvent .......................................................... 91
  • Impact Of Membrane Thickness ............................................. 91
  • Membrane Functionalization ................................................ 92
  • Membrane Pretreatment ............................................................. 93
  • Membrane Material Compositions .................................................. 93
  • Perfluorinated Polymer Membranes ................................ 94
  • Perfluorocarbonsulfonic Acid Ionomers ...................................... 95
  • Nafion Pfsa Membranes ............................................................ 96
  • Table 26 Fundamental Properties Of Nafion Pfsa Membranes........................................... 97
  • Gore Select ................................................................................... 98
  • Table 27 Conductance Comparisons .................................................... 99
  • Aciplex ........................................................................................ 100
  • Flemion ...................................................................................... 101
  • Polytetrafluoroethylene Durability Enhancement ................... 101
  • Berkeley Lab¡¯S Materials Sciences Division And Uc Berkeley¡¯S Department Of Chemical Engineering Polymer Me Mbrane ............. 102
  • Berkeley Lab¡¯S Materials Sciences ¡¦(Continued) ................... 103
  • University Of Rochester Thin Filter ............................... 104
  • Polyfuel Hydrocarbon Membrane .................................... 105
  • Polyfuel Hydrocarbon Membrane (Continued) ......................... 106
  • Polyfuel Hydrocarbon Membrane (Continued) ......................... 107
  • Mit And The University Of Pennsylvania Nanocomposite Membrane Barriers ............................ 108
  • Toray Industries Hydrocarbon Membrane ................... 109
  • Akron Polymer Systems Approach ..................................... 110
  • Daychem Laboratories Approach ....................................... 110
  • Jsr Multilayered Structure ................................................ 111
  • Ballard Power Systems Bam Membranes ........................ 111
  • Modified Polystyrene Sulfonated Membranes.......... 112
  • Victrex Polyether Ether Ketone (Peek) ......................... 113
  • Hoku Scientifics Sek Membrane .......................................... 114
  • University Of Calgary .............................................................. 115
  • Tosoh¡¯S Poly(Arylene Ether Sulfone) .............................. 115
  • Sulfonated Poly(Arylene Ether) Sulfones .................. 115
  • Sulfonated Poly(Arylene Ether) Sulfones (Continued) ............ 116
  • Table 28 Virginia Tech Bps Membrane Properties Compared With Nafion 117 ................................................................... 117
  • Functionalization And Direct Synthesis Of Sulfonated Membranes ........................................................................... 117
  • Reduced Electro-osmotic Drag ................................................. 118
  • Conductivity ............................................................................... 119
  • Argonne National Lab Dendritic Sulfonated Polyaryl Ether .......................................... 119
  • Dais Analytic Sulfonation Of Styrene Containing Block Copolymers ....................................... 120
  • Ethylene Styrene Interpolymers ............................................... 121
  • Polystyrene Sulfonic Acid/Polyvinyl Alcohol Blend ................. 121
  • Gas Technology Institute Membrane........................................ 121
  • Sulfonated Perfluorocyclobutane .............................................. 121
  • Heterocyclic And Polybenimidizole Membranes ...... 122
  • Pemeas And Celtec .................................................................. 122
  • University Of Texas Variations Of Pbi Membrane ................... 123
  • Plug Power And Doe And Pbi .................................................. 123
  • Renssalaer¡¯S Chain-transfer (Raft) Polymerization ............. 124
  • Samsung Polyimide Derivative ................................................. 124
  • Other Modifications Of Pbi........................................................ 125
  • Sulfonated Polyimides ............................................................ 126
  • Tailored Imides .......................................................................... 126
  • Poly(Bisbenzoxazole) [Pbo] ..................................................... 127
  • University Of Massachusetts Co-polymers .................. 127
  • Composite Membranes .............................................................. 128
  • Aciplex And Titanias .................................................................. 128
  • Inorganic-organic Composite ................................................... 129
  • Modified Siloxane (Ormosil) ................................................. 130
  • Organic/Heteropolyacids And Nafion ........................................ 130
  • Aniline And Perfluorosulfonic Acid Polymer ............................ 131
  • Random Fibers And Perfluorinated Membranes ...................... 131
  • Ionic Gel Fill .............................................................................. 132
  • Zirconium Phosphonate Fill ...................................................... 132
  • Oxidation Resistant Carbon Supports ...................................... 133
  • Novel And Experimental Pem Materials ........................ 133
  • Basf Polyurethane Elastomer ................................................. 134
  • Georgia Tech Triazole Booster .................................................. 134
  • Dow Xus 13204.1 ...................................................................... 134
  • Altergy Freedom Power ............................................................. 135
  • 3m Acid Functional Fluoropolymers Membrane ...................... 135
  • Glass Membranes ...................................................................... 136
  • Microcell Microfiber ................................................................... 137
  • Oak Ridge National Lab Metallized Bio-cellulosics ................ 137
  • University Of Florida Intermediate-temperature Proton-conducting Membranes ....................................................... 138
  • Membrane Companies ........................................................................... 139
  • Table 29 Companies Producing Ion Selective Membranes For Pem Fuel Cells ................................................................................. 140
  • Table 30 Estimated Pemfc Fluoropolymer Membrane Company Market Shares, 2010 (%)...................................................... 141
  • Asahi Glass Co., Ltd. .................................................................... 141
  • Asahi Kasei Chemicals Corp. .................................................. 142
  • Ballard Power Systems ........................................................... 143
  • U.S. Headquarters ..................................................................... 143
  • U.S. Headquarters (Continued) ..................................... 144
  • Dais Analytic Corp. ..................................................................... 145
  • Dupont Fuel Cells ...................................................................... 145
  • Dupont Fuel Cells (Continued) .................................. 146
  • Giner Electrochemical Systems, Llc ............................... 147
  • Golden Energy Fuel Cell Co., Ltd. ..................................... 148
  • Gore Fuel Cell Technologies .............................................. 148
  • Hoku Scientific, Inc. .................................................................. 149
  • Hydrogenics Corp. ...................................................................... 150
  • Idatech, Llc .................................................................................... 151
  • Jsr Corp. ............................................................................................ 152
  • Maxdem, Inc. (Combridge Display) ....................................... 152
  • Plug Power ..................................................................................... 153
  • Plug Power (Continued) ............................................................ 154
  • Polyfuel .......................................................................................... 155
  • Relion ................................................................................................ 155
  • Toray Industries, Inc. ............................................................... 156
  • United Technology Corp. Fuel Cells ............................... 156
  • Others ............................................................................................... 157
  • Global Pemfc Membrane Market Structure And Forecast ................................................................................................ 158
  • Pem Membrane Materials Market Share ........................ 158
  • Table 31 Proton Exchange Membrane Material By Type,2010 Versus 2015 (%) ............................................ 158
  • Pem Membrane Materials Value .......................................... 158
  • Table 32 Global Proton Exchange Membranes For Pemfcs Market By Application, Through 2015 ($Millions) .............................. 159
  • Table 33 Global Proton Exchange Membranes For Pemfcs Market By Region, Through 2015 ($ Millions)............ 159

Chapter Five: Mea, Gaseous Diffusion Layers, And Bipolar Plates ..................................................... 160

  • Gaseous Diffusion Layers ................................................................. 160
  • Gaseous Diffusion Layer Background ............................ 160
  • Attributes Of Gas Diffusion Layers .................................. 161
  • Table 34 Attributes Needed For Gas Diffusion Layer Materials ......................................... 162
  • Gas Diffusion Layer Manufacturing ................................ 163
  • Table 35 Pros And Cons Of Gdl Manufacturing Techniques ........................................... 163
  • Developments At Graftech International ................................. 164
  • Developments At ¡¦ (Continued) .................................... 165
  • Developments At Umicore Ag ................................................... 166
  • Developments At Ballard Material Products ............................ 167
  • Developments At Johnson Matthey .......................................... 168
  • Developments At Lydall, Inc. .................................................... 168
  • Developments At Mitsubishi Rayon .......................................... 169
  • Developments At Sgl Carbon Group ....................................... 169
  • Table 36 Typical Properties Of Sigracet Gas Diffusion Layer .................................................. 170
  • Developments At Toray/Mitsui .................................................. 170
  • Developments At Rensselaer Polytechnic Institute ................. 171
  • Developments At Zoltek ............................................................. 172
  • Developments At Cabot And Ird Fuel Cell ............................... 172
  • Other Developments .................................................................. 173
  • Bipolar Plates ......................................................................................... 174
  • Bipolar Plate Background .................................................... 174
  • Bipolar Plate Designs ............................................................... 175
  • Table 37 Design Considerations For Bipolar Plates ................ 175
  • Table 38 Material Types For Bipolar Plates ................................. 176
  • Corrosion Protection Of Metallic Plates .................................... 176
  • Ballard Powers¡¯ Bipolar Metal Plate .............................. 176
  • Surface Modification ....................................................... 177
  • Tech-etch Metal Plates ............................................................. 177
  • Ecpower/Sorapec Approach ...................................................... 177
  • Entegris Approach ..................................................................... 178
  • Generics Porous Plates Approach ............................................. 178
  • T8 Series .................................................................................... 179
  • Idatech Layered Bipolar Plate Assembly ................................ 179
  • Use Of Thermoplastic ................................................................. 180
  • Intelligent Energy¡¯S Proprietary Design................................... 180
  • Nisshinbo Approach ................................................................... 181
  • Pem Plates Approach ............................................................... 182
  • Illinois Urbana-champaign Fuel Cell Separator Plate Having Controlled Fiber Orientation .................................. 182
  • Plug Power Assembly ................................................................ 183
  • Porvair Approach ....................................................................... 184
  • Sgl Technologies Approach ..................................................... 184
  • Table 39 Sgl Bipolar Plate Typical Properties ........................... 185
  • Bac2 Electrophen ...................................................................... 185
  • Improved Gasket Approach ....................................................... 186
  • Acal Platinum-free Cathode ................................................... 187
  • Acal Platinum-free ¡¦ (Continued) .............................. 188
  • Federal-mogul¡¯S Liquid Elastomer Molding ............................. 189
  • Aeg Carbon Fiber-elastomer Composite Bipolar Plates ........ 189
  • Myfc Polymer Electrolyte Membrane Fuel Cell Fuelcellsticker ..................................................................... 190
  • Dmfc Anode Approaches .......................................................... 191
  • Toshiba Approach ...................................................................... 191
  • Dupont Gen Iv Approach ........................................................ 192
  • Medis Conductive Polymer Approach ....................................... 193
  • Generics Cmr Approach ........................................................... 194
  • Energy Ventures Research Approach ....................................... 194
  • Polyfuel Approach .................................................................... 195
  • Smart Fuel Cell Approach ......................................................... 195
  • Mea, Gdl, And Bipolar Plate Companies ...................................... 196
  • 10x Microstructures ................................................................. 196
  • 3m ......................................................................................................... 196
  • Asbury Graphite ........................................................................... 197
  • Ballard Power Systems ........................................................... 197
  • Dixon Ticonderoga Co. .............................................................. 197
  • Daimler ............................................................................................. 197
  • Mitsubishi Fuso ......................................................................... 198
  • Orion Bus Industries (Daimler Buses North America) ............ 198
  • Smart Gmbh .............................................................................. 198
  • Smart Gmbh (Continued) ......................................................... 199
  • Smart Gmbh (Continued) ......................................................... 200
  • Dupont Fuel Cell ........................................................................ 201
  • Elec Trochem, Inc. ....................................................................... 202
  • Entegris, Inc. ................................................................................. 203
  • General Electric ........................................................................ 203
  • General Motors, Corp. .............................................................. 204
  • Gore Fuel Cell Technologies .............................................. 205
  • Graftech International, Ltd. .............................................. 206
  • Hoku Scientific, Inc. .................................................................. 207
  • Hoku Scientific, Inc. (Continued) .............................................. 208
  • Hydrogenics Corp. ...................................................................... 209
  • Honda ................................................................................................. 209
  • Honda U.S. Headquarters ......................................................... 209
  • Horizon Fuel Cells And Riversimple ................................ 210
  • Horizon Fuel Cells And Riversimple (Continued) .................... 211
  • Icm Plastics .................................................................................... 212
  • Johnson Matthey Fuel Cells Research .......................... 212
  • Johnson Matthey Fuel Cells (Usa) .......................................... 213
  • Lynntech ......................................................................................... 213
  • Manhattan Scientifics, Inc. ................................................... 214
  • Research Headquarters ............................................................. 214
  • Materials And Electrochemical Research Corp. ...... 214
  • Mitsubishi Rayon Co., Ltd. ....................................................... 215
  • Morgan Crucible Co. .................................................................. 215
  • Morphic Technologies ............................................................. 215
  • Nedstack Fuel Cell Technology ........................................ 216
  • Nisshinbo Industries, Inc. ....................................................... 217
  • Nuvera Fuel Cells ...................................................................... 217
  • Nuvera Fuel Cells Europe ......................................................... 217
  • Palcan Fuel Cells, Ltd. ............................................................ 217
  • Plug Power ..................................................................................... 218
  • Porvair Fuel Cell Technology ............................................ 218
  • Protonex Technology Corp. .................................................. 218
  • Relion/Avista Labs ...................................................................... 219
  • Sgl Carbon ...................................................................................... 219
  • Sgl Technik .............................................................................. 220
  • Sharp Corp. ...................................................................................... 220
  • Smart Fuel Cell Ag (Sfc) .......................................................... 221
  • Smart Fuel Cell Ag (Sfc) (Continued) .................................... 222
  • Spectracorp ................................................................................... 223
  • Sumitomo Metals ......................................................................... 223
  • Superior Graphite Co. ............................................................... 224
  • Tiax ...................................................................................................... 224
  • Ticona ................................................................................................ 225
  • Timcal Graphite & Carbon ...................................................... 225
  • Toray Industries, Inc. ............................................................... 226
  • Unidym (Arrowhead Research Corp.) ................................ 226
  • Utc Power ........................................................................................ 227
  • Zoltek Materials Group .......................................................... 227
  • Global Bipolar Plates And Gdls For Pemfcs Structure Forecast ........................................................................ 227
  • Table 40 Global Pemfc Bipolar Plate And Carbon Market By Application, Through 2015 ($ Millions) ................................... 228
  • Figure 9 Global Pemfc Bipolar Plate And Carbon Market By Application, 2006-2015 ($ Millions) .............................................. 228
  • Figure 10 Global Market Shares Of Pemfc Bipolar Plate And Carbon By Type, 2010 (%) ................................................................ 229
  • Table 41 Global Pemfc Bipolar Plate And Carbon Market By Region, Through 2015 ($ Millions) ............................................. 229

Chapter Six: Catalysts And Inks .............................................................. 230

  • Background .............................................................................................. 230
  • Catalyst Durability .................................................................. 230
  • Catalyst Particle Size .............................................................. 231
  • Catalyst Coated Membranes ................................................. 231
  • Dupont Approach ...................................................................... 232
  • Polyfuel Approach .................................................................... 233
  • Aerogel Composite Approach .................................................... 233
  • Figure 11 Preparation Of Carbon Aerogel Supported Platinum .................................. 234
  • Gs Carbon Approach ................................................................. 234
  • Gs Carbon Approach (Continued) .................................. 235
  • Ramot University Approach ...................................................... 236
  • Low Catalyst Loading Approaches .................................... 236
  • Ballard Approach ....................................................................... 236
  • Combinatorial Catalyst Techniques ............................... 237
  • Innovative Materials And Nanomaterials .................... 237
  • Platinum Alloys ......................................................................... 238
  • Anode Durability ....................................................................... 239
  • Nanoparticles ............................................................................. 240
  • Kyoto University ............................................................. 240
  • Hong Kong University Of Science And Technology ........ 240
  • Los Alamos National Laboratory And Brookhaven National Laboratory .................................................. 240
  • Brown University ............................................................ 241
  • Brook Haven National Laboratory .................................. 242
  • University Of Central Florida ......................................... 243
  • Cornell University .......................................................... 244
  • Georgia Tech And Xiamen University ............................ 245
  • Georgia Tech ¡¦ (Continued) ................................... 246
  • Mit Researchers Take First Atomic-scale Compositional Images Of Fuel Cell Nanoparticles ............................................................. 247
  • Nanofibers .................................................................................. 248
  • Nanofibers (Continued) .................................................. 249
  • Nanolevel Platinum/Carbon Electrocatalyst For Cathode ........ 250
  • University Of Wisconsin-madison Nanoparticle Catalyst ........ 250
  • University Of Houston Lattice-strained Core-shell Nanoparticle Catalyst .......................................................... 251
  • Acta Base Metal Cathode Catalyst ........................................... 252
  • Lawrence Berkeley And Argonne National Laboratories Alloy ................ 253
  • Lawrence Berkeley ¡¦(Continued) ................................. 254
  • Lawrence Berkeley ¡¦(Continued) ................................. 255
  • Lawrence Berkeley ¡¦(Continued) ................................. 256
  • Nanowires .................................................................................. 257
  • University Of Rochester Sizing Nanowires .................... 257
  • Jet Propulsion Laboratory Nanophase Nickel-zirconium Alloy Approach ................................................ 258
  • University Of Texas At Austin Palladium-based Alloy Catalysts .............................................................. 259
  • Tiax, Llc Nanostructured Thin Film Catalysts .................... 260
  • Tiax, Llc ¡¦ (Continued) .............................................. 261
  • Figure 12 Projected Cost At High Volume Manufacturing (%) ........................................................ 262
  • Table 42 Performance And Cost Summary ...................................... 263
  • Sdk High-efficiency Catalysts Platinum Substitute For Pefcs ............................................................... 264
  • Washington University In St. Louis Bimetallic Fuel Cell Catalyst ...................................... 265
  • Simple Tech Heterogeneous Catalysis Technology .................. 266
  • Brown University Platinum Nanocubes ................................... 267
  • Johnson Matthey Fuel Cells, Ltd. And The Neclass Project ........................................... 268
  • University Of Rochester ¡°Black Metal¡± Approach .................... 268
  • Transition Metal Nanosized Catalysts ..................................... 269
  • Texas Tech University Platinum Nanodots ............................. 270
  • Catalyst Ink Compositions ............................................................... 270
  • Applied Research & Development Israel Formulation ..................................... 271
  • Other Catalyst Ink Formulations ..................................... 271
  • Sw Research And Gore Approach ............................................. 271
  • Utc Fuel Cells Approach .......................................................... 272
  • Jet Propulsion Laboratory Approach ........................................ 272
  • Angstron Materials Graphene .................................................. 272
  • Northwestern University And The Mccormick School Of Engineering And Applied Science Graphene Films ............ 273
  • Samsung Electronics Approach ................................................ 274
  • Carbon Composite Electrocatalyst Powders ....................... 274
  • Cabot Approach ............................................................................ 275
  • Asymtek Jet Dispensing Approach ...................................... 276
  • Catalyst And Ink Companies ............................................................ 277
  • Acta Spa ............................................................................................ 277
  • Alfa Aesar-johnson Matthey Co. ........................................ 277
  • Johnson Matthey Co. ................................................................. 278
  • Anglo Platinum ............................................................................ 279
  • Aquarius Platinum Pty, Ltd. .................................................. 280
  • Basf Corp. ......................................................................................... 280
  • Basf Corp. (Continued) ............................................................ 281
  • Basf Corp. (Continued) ............................................................ 282
  • Impala Platinum Holding, Ltd. (Implats) ......................... 283
  • Impala Platinum Holding (U.K.) .............................................. 283
  • Lonmin Platinum, Plc ................................................................ 283
  • Lonmin South Africa ................................................................. 284
  • Norilsk Nickel .............................................................................. 284
  • Stillwater Mining....................................................................... 284
  • Om Group, Inc. ................................................................................ 285
  • Quantumsphere, Inc. .................................................................. 286
  • Stillwater ...................................................................................... 287
  • Tanaka Precious Metals .......................................................... 287
  • Global Pemfcs Catalyst And Ink Structure And Forecast ................................................................................................ 287
  • Platinum Markets And Consumption ................................ 288
  • Table 43 World Mine Production And Reserves: Mine Production Pgms (Kg) ............................................................................ 289
  • Table 44 World Platinum Demand (Thousand Ozs) ...................... 289
  • Palladium Markets And Consumption ............................. 290
  • Palladium Markets And Consumption (Continued) ................. 291
  • Catalyst And Ink Value ............................................................ 292
  • Table 45 Global Pemfc Catalyst And Ink Market,Through 2015 ($ Millions) .................................................................... 292
  • Figure 13 Global Pemfc Catalyst And Ink Market,Through 2015 ($ Millions) ..................................................................... 293
  • Table 46 Global Pemfc Catalyst And Ink Market By Region, Through 2015 ($ Millions) .................................................. 293

Chapter Seven: Industry Structure And Competitive Aspects ....................................................... 294

  • Industry Environment And Trade Practices .......................... 294
  • Environmental Issues .............................................................. 295
  • Environmental Issues (Continued) ........................................... 296
  • Pemfc Regulatory Issues And Government Involvement ........................................ 297
  • U.S. Doe Direct Pem Fuel Cell Funding ................................ 297
  • Topic 1 Alternative Electrode Deposition Processes ..... 297
  • Topic 2 Novel Mea Manufacturing ............................... 297
  • Topic 3 Rapid Mea Conditioning .............................. 298
  • Topic 4 Process Modeling For Fuel Cell Stacks .............. 298
  • Topic 5 Process And Device For Cost Effective Testing Of Cell Stacks ................................................ 299
  • Topic 6 Manufacturing Technologies For Reducing The Cost Of High-pressure Composite Conformable Tanks ................................................... 299
  • U.S. Federal Fuel Cell Vehicle Funding ................................... 300
  • U.S. Federal ¡¦ (Continued) ........................................... 301
  • U.S. Federal ¡¦ (Continued) ........................................... 302
  • U.S. Federal ¡¦ (Continued) ........................................... 303
  • Overall U.S. Federal Fuel Cell Funding ................................... 304
  • Table 47 2010 Budget Hydrogen And Fuel Cell Technologies Funding Profile By Subprogram ($Thousands) .................... 304
  • Table 47 (Continued) .................................................................................... 305
  • Overall U.S. Federal ¡¦ (Continued) .............................. 306
  • U.S. Fuel Cell Council Analysis Of Funding Priorities ............ 307
  • U.S. Fuel Cell ¡¦ (Continued) ......................................... 308
  • Office Of Science ......................................................................... 309
  • National Hydrogen Association ................................................ 310
  • National Science Foundation .................................................... 310
  • Department Of Defense .............................................................. 311
  • Army Research Laboratory ............................................ 311
  • Usaf Research Laboratory ............................................ 311
  • Naval Research Laboratory ............................................ 312
  • National Aeronautics And Space Administration (Nasa) ....... 312
  • Jet Propulsion Laboratory .............................................. 312
  • Global Incentives And Research Efforts ................................... 313
  • Academic Institutions¡¯ Involvement In Fuel Cell Development ............................................................................ 314
  • Table 48 Major Institutional Research Into Pem Fuel Cells .............................................................................................................. 314
  • Mea Distribution Channels .............................................................. 315
  • Industry Purchasing Influences And Prices ......................... 315
  • Industry Purchasing Influences ¡¦ (Continued) ....... 316
  • Industry Purchasing Influences ¡¦ (Continued) ....... 317
  • Table 49 Historic Platinum Prices (Dollars Per Tr Oz) ........... 318
  • Table 50 Historic Palladium Prices (Dollars Per Tr Oz) ......... 318
  • Life-cycle Costs ........................................................................... 319
Title: Materials for Proton Exchange Membranes and Membrane Electrode Assemblies for PEM Fuel Cells
 
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